This volume contains the Proceedings of the Fifth Scientific Meeting of the Spanish Astronomical Society (Sociedad Espanola de Astronomfa, SEA). The meeting was held at the Universidad de Castilla La Mancha in Toledo, from September 9 to 13, 2002. The event brought together 219 participants who pre sented their latest results in many different subjects. In comparison with the previous scientific meetings of the Society, the numbers of oral talks and poster contributions (122 and 64, respectively) are rapidly increasing, confirming that the SEA conferences are becoming a point of reference to assess the interests and achievements of astrophysical research in Spain. During the meeting, the SEA made public the granting of the Prize to the Best Spanish Ph. D. Thesis in As tronomy and Astrophysics for the period 2000-2001 ex aequo to Dr. A. Zurita and Dr. E. Villaver. This is the second time that the SEA is awarding this prize, which aim is to encourage young spanish astrophysicists to pursue a high level scientific career. The Society is indebted to the Universidad de Castilla La Mancha, and, in particular, to the San Pedro Martir staff, for its hospitality. It is also indebted to the Local Organizing Committee for its dedication and the good atmosphere that prevailed at any moment, and to the Scientific Organizing Committee for its excel lent work.